rapid, convenient and solventless green approach for the synthesis of aryloximes using zno nanoparticles as an efficient catalyst
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abstract
freshly prepared zno nanoparticles were used as an effective heterogeneous base catalyst for the synthesis of aryloximes. the conversion of arylaldehydes and arylketones into the corresponding oximes (up to quantitative yields) was achieved by simply mixing the liquid reactants and hydroxylamine hydrochloride with zno nanoparticles under solvent-free condition. the procedure was carried out under wet conditions for solid reactants. the advantages of this method include mild reaction conditions, one-pot procedure, operational simplicity and use of inexpensive and non-toxic catalyst.
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Rapid, convenient and solventless green approach for the synthesis of aryloximes using ZnO nanoparticles as an efficient catalyst
Freshly prepared ZnO nanoparticles were used as an effective heterogeneous base catalyst for the synthesis of aryloximes. The conversion of arylaldehydes and arylketones into the corresponding oximes (up to quantitative yields) was achieved by simply mixing the liquid reactants and hydroxylamine hydrochloride with ZnO nanoparticles under solvent-free condition. The procedure was carried out und...
full textRapid, convenient and solventless green approach for the synthesis of aryloximes using ZnO nanoparticles as an efficient catalyst
Freshly prepared ZnO nanoparticles were used as an effective heterogeneous base catalyst for the synthesis of aryloximes. The conversion of arylaldehydes and arylketones into the corresponding oximes (up to quantitative yields) was achieved by simply mixing the liquid reactants and hydroxylamine hydrochloride with ZnO nanoparticles under solvent-free condition. The procedure was carried out und...
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A rapid, convenient, solventless green approach for the synthesis of oximes using grindstone chemistry
BACKGROUND Synthesis of oximes is an important reaction in organic chemistry, because these versatile oximes are used for protection, purification, and characterization of carbonyl compounds. Nitriles, amides via Beckmann rearrangement, nitro compounds, nitrones, amines, and azaheterocycles can be synthesised from oximes. They also find applications for selective α-activation. In inorganic chem...
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1,2-Diketones have been reacted in one-pot method with 1,2-diamines at room temperature with ZnO nanoparticles as a catalyst. ZnO nanoparticles as an available and reusable catalyst is used for the synthesis of Quinoxalinein improved yields.
full textZnO nanoparticles as an Efficient and Reusable Catalyst for Synthesis of Quinoxaline under Solvent Free Condition
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Journal title:
iranian journal of catalysisPublisher: islamic azad university, shahreza branch
ISSN 2252-0236
volume 5
issue 1 2015
Keywords
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